Nanowire semiconductor device including lateral-etch barrier region

ABSTRACT

A semiconductor device includes a semiconductor-on-insulator water having a buried layer. The buried layer includes therein opposing etch barrier regions and a gate region between the etch barrier regions. The semiconductor device further includes at least one nanowire having a channel portion interposed between opposing source/drain portions. The channel portion is suspended in the gate region. A gate electrode is formed in the gate region, and completely surrounds all surfaces of the suspended nanowire. The buried layer comprises a first electrical insulating material, and the etch barrier regions comprising a second electrical insulating material different from the first electrical insulating material.

DOMESTIC PRIORITY

This application is a divisional of U.S. patent application Ser. No.15/229,690, filed Aug. 5, 2016, which is a continuation of U.S. patentapplication Ser. No. 14/950,011, filed Nov. 24, 2015, which is acontinuation of U.S. patent application Ser. No. 14/748,521, filed Jun.24, 2015, the disclosures of which are incorporated by reference hereintheir entirety.

BACKGROUND

The present invention relates to semiconductor devices, and morespecifically, to nanowire field effect transistor (FET) devices.

The use of non-planar semiconductor devices such as, for example, FinFET devices (i.e., FinFETs) is desirable due the ability to reduce theoverall size of the semiconductor device. The fabrication of non-planarsemiconductor devices such as, for example, gate-all-around nanowire FETdevices, typically utilizes a semiconductor-on-insulator (SOI) substrateto reduce parasitic device capacitance. SOI substrates typically includea bulk substrate, a buried insulator layer located atop the bulksubstrate, and a semiconductor-on-insulator (SOI) layer located atop theburied insulator layer.

Nanowire FET devices have become a popular non-planar semiconductordevice due to their improved channel electrostatics control. Formationof nanowire FET devices typically includes forming one or moresemiconductor fins atop a SOI layer and then undercutting the finslocated in the gate region to form suspended fins, typically referred toas suspended nanowires. The undercutting process allows access to thecomplete surface of the suspended nanowires. In this manner, a gateelectrode formed in the gate region contacts all sides of the nanowireachieving a gate-all-around configuration which improves channelelectrostatics control. However, conventional undercutting processesused to form the suspended nanowires in the gate region have tendency toetch in an isotopic manner which laterally extends the gate region. Insome instances, the lateral undercut beneath a raised source/drainregion which can cause an electrical short circuit path between the gateelectrode formed in the gate region and epitaxial material used to formraised source/drain regions of the device.

SUMMARY

According to at least one non-limiting embodiment of the presentinvention, a method of fabricating a semiconductor device comprisesforming a semiconductor-on-insulator (SOI) wafer including a buriedinsulator layer. The buried insulator layer includes etch barrierregions comprising a first electrical insulator material, and anundercutting region interposed between the etch barrier regions. Theundercutting region comprises a second electrical insulator materialdifferent from the first electrical insulator material. The methodfurther includes forming at least one semiconductor fin on an uppersurface of the buried insulator layer. The at least one semiconductorfin includes a channel portion formed on the undercutting region andsource/drain portions formed on respective etch barrier regions. Themethod further includes performing an etching process that etches theundercutting region to undercut the channel portion while the secondelectrical insulating material prevents etching beneath the source/drainportions of the at least one semiconductor fin.

According to another non-limiting embodiment of the invention, asemiconductor device includes a semiconductor-on-insulator wafer havinga buried oxide layer. The buried oxide layer includes therein opposingetch barrier regions and a gate region between the etch barrier regions.The semiconductor device further includes at least one nanowire having achannel portion interposed between opposing source/drain portions. Thechannel portion is suspended in the gate region. A gate electrode isformed in the gate region, and completely surrounds all surfaces of thesuspended nanowire. The buried oxide layer comprises a first electricalinsulating material, and the etch barrier regions comprising a secondelectrical insulating material different from the first electricalinsulating material.

Additional features are realized through the techniques of the presentinvention. Other embodiments are described in detail herein and areconsidered a part of the claimed invention. For a better understandingof the invention with the features, refer to the description and to thedrawings.

BRIEF DESCRIPTION OF THE DRAWINGS

The subject matter which is regarded as the invention is particularlypointed out and distinctly claimed in the claims at the conclusion ofthe specification. The forgoing features are apparent from the followingdetailed description taken in conjunction with the accompanyingdrawings. With reference to FIGS. 1-10, a series of views illustrating amethod of forming a nanowire FET device according to exemplaryembodiments of the present teachings, in which:

FIG. 1 illustrates an semiconductor-on-insulator (SOI) wafer including aburied insulator layer and a plurality of semiconductor fins on an uppersurface of the buried insulator layer;

FIGS. 2A-2B illustrates the wafer of FIG. 1 after forming a dummy gateon an upper surface of the buried insulator layer to cover a centerportion of the fins and define opposing source/drain regions;

FIG. 3 illustrates the wafer of FIG. 2 following deposition of a blockspacer layer that covers the dummy gate and the fins;

FIG. 4 illustrates the wafer of FIG. 3 after etching the block spacerlayer to re-exposed the source/drain regions of the fins whilemaintaining gate spacers on opposing sidewalls of the dummy gate;

FIG. 5 illustrates the wafer of FIG. 4 undergoing an ion implantationprocess to form lateral-etch barrier regions in the buried insulatorlayer;

FIG. 6 illustrates the wafer of FIG. 5 after epitaxially growing raisedsource/drain regions from the exposed fins and onto the lateral-etchbarrier regions to merge together the source/drain regions of the fins;

FIG. 7 illustrates the wafer of FIG. 6 following deposition of aflowable insulator material on the an upper surface of the raisedsource/drain epi regions and planarizing the flowable insulator layerflush with an upper surface of the dummy gate;

FIG. 8 illustrates the wafer of FIG. 7 after removing the dummy gate toform a trench that exposes channel portions of the fins and the buriedinsulator layer located between the gate spacers;

FIG. 9 illustrates the wafer of FIG. 8 following a laterally-controlledetch to form suspended nanowires that are anchored by the gate spacers;and

FIG. 10 illustrates the wafer of FIG. 9 after depositing a gate materialin the trench to form a gate electrode that contacts all surfaces of thesuspended nanowires.

DETAILED DESCRIPTION

Various embodiments provide a nanowire FET device including alateral-etch barrier layer configured to prevent lateral etching beneaththe gate spacers when undercutting semiconductor fins to form suspendednanowires in the gate region. According to an embodiment, nitrogen (N)or carbon (C) ions, for example, are implanted in exposed regions of aburied insulation layer included in a semiconductor-on-insulator (SOI)wafer to form a doped-oxide lateral-etch barrier layer at opposing sidesof a region of the buried insulator layer located beneath gate region. Awet etch process using a hydrofluoric (HF) solution, for example, may beused to etch the buried insulator layer and form the suspendednanowires. The doped-oxide lateral-etch barrier layer has a slower etchrate with respect to the material of the remaining buried insulatorlayer. Accordingly, the region of the buried insulator layer locatedbeneath the semiconductor fins can be etched to undercut the fins andform the suspended nanowire, while the later-etch barrier layer preventsthe HF wet etch solution from etching laterally beneath the fins andgate spacers located in the designated source/drain regions. In thismanner, device shorting can be prevented when depositing a metalmaterial in the gate region to form a gate-all-around nanowire FETdevice.

With reference now to FIG. 1, a semiconductor device 100 including asemiconductor-on-insulator (SOI) wafer 102 is illustrated according to anon-limiting embodiment. The SOI wafer 102 extends along a firstdirection (e.g., X-axis) to define a wafer length, a second direction(e.g., Y-axis) to define a wafer width, and a third direction (e.g.,Z-axis) to define a wafer height. The SOI wafer 102 further includes abulk layer 104, a buried insulator layer 106 formed on an upper surfaceof the bulk layer 104, and one or more semiconductor fins 108 formed onan upper surface of the buried insulator layer 106. The bulk layer 104is formed of silicon (Si), for example, and has a height (e.g., alongthe Z-axis) ranging from approximately 2 millimeters (mm) toapproximately 6 mm. The buried insulator layer 106 is formed of a firstelectrical insulating material such as silicon dioxide (SiO₂), forexample, and has a height (e.g., along the Z-axis) ranging fromapproximately 100 nanometers (nm) to approximately 150 nm. The fins 108can be formed according to a well-known side image transfer (SIT)process to pattern an active semiconductor layer, e.g., a silicon layer(not shown) formed on an upper surface of the buried insulator layer104. More specifically, the SIT process typically utilizes a blockhardmask layer (not shown) formed on an upper surface of the activesemiconductor layer. The block hardmask layer is then patterned todesignate the desired locations of the fins 108, and the pattern istransferred into the active semiconductor layer. The result is one ormore semiconductor fins 108 atop the buried insulator layer 104.According to a non-limiting embodiment, the fins 108 have a width (e.g.,along the Y-axis) ranging from approximately 6 nm to approximately 12nm, and a height (e.g., along the Z-axis) ranging from approximately 6nm to approximately 45 nm.

Turning now to FIGS. 2A-2B, the semiconductor device 100 is illustratedfollowing a gate formation process that forms a dummy gate 110 atop theburied insulator layer 106. The dummy gate 110 is formed of polysilicon(poly-Si), for example, and covers a middle portion of the fins 108.According to a non-limiting embodiment, the dummy gate 110 has a length(e.g., along the X-axis) ranging from approximately 10 nm toapproximately 25 nm, and a height (e.g.., along the Z-axis) ranging fromapproximately 100 nm to approximately 120 nm.

The dummy gate 110 defines various regions of the buried insulator layer106 and various portions of the fins 108 as illustrated in FIG. 2B.Namely, the region of the buried insulator layer 106 covered by thedummy gate 110 is hereinafter referred to as an undercutting region 107,while regions of the buried insulator layer 106 located at opposingsides of the dummy gate 110 are hereinafter referred to as exposedregions 109. Accordingly, the fins 108 include a channel portion 111interposed between opposing source/drain portions 113. The channelportion 111 (covered by the dummy gate 110) is formed on an uppersurface of the exposed regions 107, while the uncovered source/drainportions 113 are formed on an upper surface of a respective exposedregion 109.

Referring now to FIG. 3, a block spacer layer 112 is deposited atop theburied insulator layer 106 using, for example, a chemical-vapordeposition (CVD) process. The block spacer layer 112 covers thesource/drain portions 113 of the fins 108 and the dummy gate 110.According to a non-limiting embodiment, the block spacer layer 112 isformed of a low-dielectric (low-k) material including, but not limitedto, silicon nitride (SiN), silicon carbon nitride (SiCN) or siliconboron carbon nitride (SiBCN). The block spacer layer 112 can be used toform gate spacers (not shown in FIG. 3) as discussed in greater detailbelow.

Referring to FIG. 4, the semiconductor device 100 is illustratedfollowing an etching process that forms gate spacers 114 on opposingsidewalls of the dummy gate 110. Various etching process may beperformed including, for example, an anisotropic (directional) reactiveion etch (RIE) process that is selective to the fin material (e.g., Si),the dummy gate material (e.g., poly-Si), and the buried insulator layermaterial (e.g., SiO₂). In this manner, the gate spacers 114 are formedon sidewalk of the dummy gate 110 while revealing the source/drainportions 113 of the fin 108 and the exposed regions of the buriedinsulator layer 106.

Turning to FIG. 5, an ion implantation process is performed convert aportion of the exposed regions 107 into etch barrier regions 116 formedof a second electrical insulating material different from the firstelectrical insulating material of the non-implanted buried insulatorlayer 106 (e.g., SiO₂). More specifically, the ion implantation processincludes implanting nitrogen (N) ions or carbon (C) ions into the buriedinsulator layer 106. In the case where nitrogen (N) ions are implanted,a nitrogen-doped oxide (e.g., SiON) etch barrier region 116 formed. Inthe case where carbon (C) ions are implanted, a carbon-doped oxide(e.g., SiOC) etch barrier region 116 formed. The energy of the ionimplantation source can be adjusted to control the desired depth of theetch barrier region 116. That is, increasing the energy of the ionimplantation source increases the depth of the ion implantation andcontrols the vertical thickness (e.g.., along the Z-axis) of the etchbarrier region 116. According to a non-limiting embodiment, the etchbarrier region 116 has a vertical thickness ranging from approximately10 nm to approximately 40 nm. It should also be appreciated that theions (e.g., the nitrogen ions or carbon ions) change the materialcomposition of only the buried insulator layer 106. In this manner, theions travel through the fins 108 without changing the materialcomposition thereof. Accordingly, a mask is not needed to cover the fins108 when performing the ion implantation process.

In either case described above, the second insulating material (e.g.,SiON or SiOC) of the etch barrier layer 116 has an etch rate that isless than the etch rate of the first electrical insulating material(e.g., SiO₂) when exposed to various etching process such as, forexample, a wet etching process utilizing a hydrofluoric (HF) solution.In this manner, regions of the buried insulator layer 106 formed of thefirst electrical insulating material (e.g., the undercutting region 107)can be etched while preserving portions of the buried insulator layer106 formed of the second electrical insulating material (e.g., the etchbarrier regions 116) as discussed in greater detail below.

Turning now to FIG. 6, the semiconductor device 100 is illustratedfollowing a well-known epitaxy process to grow a semiconductor materialfrom the fins 108 and onto an upper surface of the etch barrier regions116. The epitaxially grown semiconductor material may comprise, forexample, silicon (Si) doped with phosphate (P) when forming a n-typesemiconductor device. Alternatively, the epitaxially grown semiconductormaterial may comprise silicon (Si) or silicon germanium (Site) dopedwith boron (B) when forming a p-type semiconductor device. In thismanner, raised source/drain contacts 118 are formed that cover the fins108 and merge together the source/drain portions 113.

Referring to FIG. 7, a flowable insulator material 120 is deposited atopthe raised source/drain contacts 118. More specifically, the flowableinsulator material 120 is deposited on an upper surface of thesource/drain contacts 118 to cover the gate spacers 114 and dummy gate110. A chemical-mechanical polishing (CMP) procedure is subsequentlyperformed until reaching the upper surface of the dummy gate 110 asfurther illustrated in FIG. 7. In this manner, the upper surface of thedummy gate 110, the upper surface of the gate spacers 114, and the uppersurface of the flowable insulator material 120 are flush with oneanother. The flowable insulator material 120 is formed of, for example,a flowable oxide (FOX) material (e.g., SiO₂), and can serve toelectrically isolate the raised source/drain contacts 118 fromneighboring semiconductor devices (not shown) formed near thesemiconductor 100.

Turning to FIG. 8, the dummy gate 110 is removed to form a trench 12 inthe gate region between the gate spacers 114. The dummy gate removalprocess may include a dry etch process followed by a wet etch cleaningprocess. Namely, a selective dry RIE that attacks only the dummy gatematerial is used to remove the dummy gate (not shown in FIG. 8) from thegate region and form the trench 122. In this manner, the dry RIE can beperformed without requiring a mask to cover the flowable insulatormaterial 120. Subsequently, a wet cleaning process can be applied toremove any residual dummy gate material from within the trench 122. Thewet cleaning process may use, for example, a diluted HF and ammoniumhydroxide (NH₄OH) solution. Since the wet etch time is short, anyrecession of the flowable insulator material 120 is negligible.Following removal of the dummy gate, the trench 122 exposes the channelportion 111 of the tins 108 and the undercutting region 107 of theburied insulator layer 106 as further illustrated in FIG. 8.

Referring to FIG. 9, the semiconductor device 100 is illustrated afterselectively etching the undercutting region 107 to form a void 124between the buried insulator layer 106 and the channel portion 111 ofthe fins 108. In this manner, one or more suspended fins, hereinafterreferred to as suspended nanowires 108, are formed in the trench 122.The void 124 may define a distance between a remaining portion of theundercutting region 107 and the bottom surface of the fin channelportion 111 that ranges, for example, from approximately 20 nm toapproximately 30 nm.

As described above, the second insulating material (e.g., SiON or SiOC)of the etch barrier layer 116 has an etch rate that is less than theetch rate of the first electrical insulating material (e.g., SiO₂) whenexposed to various etching process such as, for example, a wethydrofluoric (HF) etching solution. In this manner, the undercuttingregion 107 can be selectively etched while the etch barrier regions 116are unetched and remain preserved. As a result, a bottom surface of thechannel portion 111 is formed flush with an upper portion of the etchbarrier regions 116, and a bottom portion of the gate spacers 114. Thatis, unlike conventional nanowire FET devices formed by undercutting thesemiconductor fins, at least one embodiment of the invention excludesundercuttings that extend laterally (e.g., along the X-axis) beneathsource/drain portions of the nanowire 108, beneath the spacers 114,and/or beneath the raised source/drain contacts 118.

Turning now to FIG. 10, a replacement metal gate stack 126 is depositedin the previously formed trench (not shown in FIG. 10). Morespecifically, the gate stack material can be deposited atop the flowableinsulator material 120 and into the trench to completely surround thesuspended nanowires 108. The gate materials can be deposited usingatomic layer deposition (ALD), for example, and can include one or morehigh-k gate dielectric materials including, but not limited to, hafniumsilicate (HfSiO₄), zirconium silicate (ZrSiO₄), hafnium dioxide (HfO₂),and zirconium dioxide (ZrO₂). The gate materials may also include one ormore gate conductor materials such as tungsten (W). Although also notillustrated, the previously formed trench 122 may also be lined with awork function metal film after depositing the high-k gate dielectriclayer and prior to deposing the gate material 126 to control the voltagethreshold of the device as understood by one of ordinary skill in theart.

Subsequently, a chemical-mechanical polishing (CMP) procedure isperformed until reaching the upper surface of the flowable insulatorlayer 120. In this manner, the upper surface of the gate material 126 isformed flush with the upper surface of the gate spacers 114, and theupper surface of the flowable insulator material 120. Accordingly, agate electrode 126 is formed that completely surrounds all surfaces ofthe suspended nanowire 108 so as to fabricate a nanowire FET device 100having a gate-all-around configuration as further illustrated in FIG.10. Although not illustrated, electrically conductive vias (not shown)may be formed through the flowable insulator material 120 to contact theraised source/drain contacts 118. Electrically conductive source/drainelectrodes (not shown) are then formed against the vias to establish anelectrical connection with the merged source/drain portions of thenanowires 111 as understood by one of ordinary skill in the art.

As described in detail above, various embodiments provide a nanowire FETdevice including an etch barrier layer configured to prevent lateraletching beneath source/drain portions of the nanowire, beneath thespacers, and/or beneath the raised source/drain contacts whenundercutting semiconductor fins to form suspended nanowires in the gateregion. In this manner, device shorting between the gate electrode andthe raised source/drain contacts can be prevented.

The descriptions of the various embodiments of the present inventionhave been presented for purposes of illustration, but are not intendedto be exhaustive or limited to the embodiments disclosed. Manymodifications and variations will be apparent to those of ordinary skillin the art without departing from the scope and spirit of the describedembodiments. The terminology used herein was chosen to best explain theprinciples of the embodiments, the practical application or technicalimprovement over technologies found in the marketplace, or to enableothers of ordinary skill in the art to understand the embodimentsdisclosed herein.

The terminology used herein is for the purpose of describing particularembodiments only and is not intended to be limiting of the invention. Asused herein, the singular forms “a”, “an” and “the” are intended toinclude the plural forms as well, unless the context clearly indicatesotherwise. It will be further understood that the terms “comprises”and/or “comprising,” when used in this specification, specify thepresence of stated features, integers, steps, operations, elements,and/or components, but do not preclude the presence or addition of onemore other features, integers, steps, operations, element components,and/or groups thereof.

The corresponding structures, materials, acts, and equivalents of allmeans or step plus function elements in the claims below are intended toinclude any structure, material, or act for performing the function incombination with other claimed elements as specifically claimed. Thedescription of the present invention has been presented for purposes ofillustration and description, but is not intended to be exhaustive orlimited to the invention in the form disclosed. Many modifications andvariations will be apparent to those of ordinary skill in the artwithout departing from the scope and spirit of the invention. Theembodiment was chosen and described in order to best explain theprinciples of the inventive teachings and the practical application, andto enable others of ordinary skill in the art to understand theinvention for various embodiments with various modifications as aresuited to the particular use contemplated.

The flow diagrams depicted herein are just one example. There may bemany variations to this diagram or the operations described thereinwithout departing from the spirit of the invention. For instance, theoperations may be performed in a differing order or operations may beadded, deleted or modified. All of these variations are considered apart of the claimed invention.

While various embodiments have been described, it will be understoodthat those skilled in the art, both now and in the future, may makevarious modifications which fall within the scope of the claims whichfollow. These claims should be construed to maintain the properprotection for the invention first described.

What is claimed is:
 1. A semiconductor device, comprising: asemiconductor-on-insulator wafer including a buried insulator layer, theburied insulator layer including therein opposing etch barrier regionsand a gate region between the etch barrier regions; at least onenanowire including a channel portion interposed between opposingsource/drain portions, the channel portion suspended in the gate region;and a gate electrode in the gate region, the gate electrode completelysurrounding the suspended nanowire, wherein the buried insulator layercomprises a first electrical insulating material, and the etch barrierregions comprises a second electrical insulating material different fromthe first electrical insulating material, and wherein the etch barrierregions are between the at least one nanowire and the buried insulatorlayer, and opposing sidewalls of the gate electrode contact the etchbarrier regions.
 2. The semiconductor device of claim 1, wherein abottom surface of the channel portion is flush with an upper portion ofthe etch barrier regions.
 3. The semiconductor device of claim 2,wherein the upper portion of the etch barrier regions excludeundercuttings beneath source/drain portions of the at least onenanowire.
 4. The semiconductor device of claim 1, further comprisingspacers on the sidewalls of the gate electrode, the spacers including abottom portion atop the etch barrier regions.
 5. The semiconductordevice of claim 4, wherein undercuttings are excluded from beneath thespacers.
 6. The semiconductor device of claim 4, wherein inner sidewallsof the spacers are flush with inner sidewalls of the etch barrierregions.
 7. The semiconductor device of claim 6, further comprisingepitaxial raised source/drain regions covering the source/drain portionsof the at least one nanowire.
 8. The semiconductor device of claim 7,wherein undercuttings are excluded from beneath the epitaxial raisedsource/drain regions.
 9. The semiconductor device of claim 7, whereinthe etch barrier regions are interposed between the first electricalinsulating material and the epitaxial raised source/drain regions. 10.The semiconductor device of claim 1, wherein the first electricalinsulating material has a first etch rate and the second electricalinsulating material has a second etch rate different than the first etchrate.
 11. The semiconductor device of claim 10, wherein the first etchrate is than the second etch rate.
 12. The semiconductor device of claim11, wherein the first electrical insulating material comprises silicondioxide.
 13. The semiconductor device of claim 12, wherein the secondelectrical insulating material comprises nitrogen-doped oxide.
 14. Thesemiconductor device of claim 12, wherein the second electricalinsulating material comprises carbon-doped oxide.
 15. The semiconductordevice of claim 1, wherein the etch barrier regions have a verticalthickness ranging from 10 nanometers (nm) to 40 nm.
 16. Thesemiconductor device of claim 1, wherein a portion of the buriedinsulator layer beneath the suspended channel portion defines anundercutting region.
 17. The semiconductor device of claim 16, wherein adistance between the undercutting region and a bottom surface of thesuspended channel portion ranges from 20 nanometers (nm) to 30 nm. 18.The semiconductor device of claim 8, wherein the epitaxial raisedsource/drain regions comprise silicon (Si) doped with phosphorus (P).19. The semiconductor device of claim 8, wherein the epitaxial raisedsource/drain region comprises silicon (Si).
 20. The semiconductor deviceof claim 8, wherein the epitaxial raised source/drain regions comprisessilicon germanium (SiGe).